Cacodyl oxide

Cacodyl oxide
Names
Preferred IUPAC name
Dimethylarsinous anhydride
Other names
TL-297
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.376.169
  • InChI=1S/C4H12As2O/c1-5(2)7-6(3)4/h1-4H3 N
    Key: LOKPKYSOCCPWIZ-UHFFFAOYSA-N N
  • InChI=1/C4H12As2O/c1-5(2)7-6(3)4/h1-4H3
    Key: LOKPKYSOCCPWIZ-UHFFFAOYAL
  • C[As](C)O[As](C)C
Properties
C4H12As2O
Molar mass 255.98 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Cacodyl oxide is a chemical compound of the formula [(CH3)2As]2O. This organoarsenic compound is primarily of historical significance since it is sometimes considered to be the first organometallic compound synthesized in relatively pure form.

"Cadet's fuming liquid", which is composed of cacodyl and cacodyl oxide, was originally synthesized by heating potassium acetate with arsenic trioxide. It has a disagreeable odor and is toxic.

The molecular structure of [Ph2As]2O (Ph = phenyl), the tetraphenyl analogue of cacodyl oxide, has been established by X-ray crystallography.