Vanadium dioxide fluoride

Vanadium dioxide fluoride
Identifiers
CAS Number	14259-82-6;
3D model (JSmol)	Interactive image;
	InChI InChI=1S/FH.2O.V/h1H;;;/q;;;+1/p-1 Key: LEFMSXWIPZZRSQ-UHFFFAOYSA-M;
	SMILES O=[V](F)=O;
Properties
Chemical formula	FO2V
Molar mass	101.938 g·mol−1
Appearance	orange solid
Density	3.41 g/cm3
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Vanadium dioxide fluoride is the inorganic compound with the formula VO₂F. It is an orange diamagnetic solid. The compound adopts the same structure as iron(III) fluoride, with octahedral metal centers and doubly bridging oxide and fluoride ligands. It is prepared by the reaction of vanadium pentoxide and vanadium(V) oxytrifluoride:

V₂O₅ + VOF₃ → 3VO₂F

An alternative synthesis using hexamethyldisiloxane:

(CH₃)₃SiOSi(CH₃)₃ + VOF₃ → VO₂F + 2 (CH₃)₃SiF

Identifiers

CAS Number	14259-82-6
3D model (JSmol)	Interactive image
InChI InChI=1S/FH.2O.V/h1H;;;/q;;;+1/p-1 Key: LEFMSXWIPZZRSQ-UHFFFAOYSA-M
SMILES O=[V](F)=O
Properties
Chemical formula	FO₂V
Molar mass	101.938 g·mol⁻¹
Appearance	orange solid
Density	3.41 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references