Tetrachloroaluminate

Tetrachloroaluminate
Names
IUPAC name
Tetrachloroaluminate(1–)
Systematic IUPAC name
Tetrachloroaluminate(1-)
Other names
 
  • Aluminate(1-), tetrachloro
  • tetrachloridoaluminate(1-)
  • tetrachloridoaluminate(1-); tetrachloroalumanuide
  • tetrachloroalumanuide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
2297
  • InChI=1S/Al.4ClH/h;4*1H/q+3;;;;/p-4
    Key: BXILREUWHCQFES-UHFFFAOYSA-J
  • InChI=1S/Al.4ClH/h;4*1H/q+3;;;;/p-4
    Key: BXILREUWHCQFES-UHFFFAOYSA-J
  • Cl[Al-](Cl)(Cl)Cl
Properties
AlCl4−
Molar mass 168.78 g·mol−1
Structure
Td
Tetrahedral
Hybridisation sp3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tetrachloroaluminate [AlCl4]− is an anion formed from aluminium and chlorine. The anion has a tetrahedral shape and is isoelectronic with silicon tetrachloride. Some tetrachloroaluminates are soluble in organic solvents, creating an ionic non-aqueous solution, making them suitable as component of electrolytes for batteries. For example, lithium tetrachloroaluminate is used in some lithium batteries.

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