Tantalum carbide

Tantalum carbide
Names
IUPAC name
Tantalum carbide
Other names
Tantalum(IV) carbide
Identifiers
  • (TaC): 12070-06-3 Y
  • (TaC0.5): 12070-07-4 N
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.914
EC Number
  • (TaC): 235-118-3
  • (TaC0.5): 235-119-9
UNII
  • (TaC): InChI=1S/C.Ta/q-1;+1
    Key: DUMHRFXBHXIRTD-UHFFFAOYSA-N
  • (TaC0.5): InChI=1S/C.2Ta
    Key: VDBAWDHDCVOEAA-UHFFFAOYSA-N
  • (TaC): [Ta+]#[C-]
  • (TaC0.5): [C].[Ta].[Ta]
Properties
TaC
Molar mass 192.96 g/mol
Appearance Brown-gray powder
Odor Odorless
Density 14.3–14.65 g/cm3 (TaC)
15.1 g/cm3 (TaC0.5)
Melting point 3,768 °C (6,814 °F; 4,041 K)
(TaC)
3,327 °C (6,021 °F; 3,600 K)
(TaC0.5)
Boiling point 4,780–5,470 °C (8,640–9,880 °F; 5,050–5,740 K)
(TaC)
Insoluble
Solubility Soluble in HF-HNO3 mixture
Thermal conductivity 21 W/(m·K)
Thermochemistry
36.71 J/(mol·K)
42.29 J/(mol·K)
−144.1 kJ/mol
Related compounds
Related refractory ceramic materials
Related compounds
Hafnium carbide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tantalum carbides (TaC) form a family of binary chemical compounds of tantalum and carbon with the empirical formula TaCx, where x usually varies between 0.4 and 1. They are extremely hard, brittle, refractory ceramic materials with metallic electrical conductivity. They appear as brown-gray powders, which are usually processed by sintering.

Being important cermet materials, tantalum carbides are commercially used in tool bits for cutting applications and are sometimes added to tungsten carbide alloys.

The melting points of tantalum carbides was previously estimated to be about 3,880 °C (4,150 K; 7,020 °F) depending on the purity and measurement conditions; this value is among the highest for binary compounds. And only tantalum hafnium carbide was estimated to have a higher melting point of 3,942 °C (4,215 K; 7,128 °F). However new tests have conclusively proven that TaC actually has a melting point of 3,768 °C and both tantalum hafnium carbide and hafnium carbide have higher melting points.