Salcomine

Salcomine
Names
Other names
  • N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
  • Co(salen)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.541
UNII
  • InChI=1S/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2/b17-11+,18-12+; N
    Key: NPAQSKHBTMUERN-OYJDLGDISA-L N
  • ionic form: c1cc(c(cc1)[O-])/C=N/CC/N=C/c2c(cccc2)[O-].[Co+2]
  • coordination form: C1C[N+]2=Cc0ccccc0O[Co-2]23Oc0ccccc0C=[N+]13
Properties
C16H14CoN2O2
Molar mass 325.233 g·mol−1
Hazards
GHS labelling:
Warning
H315, H319, H335
P261, P264, P271, P280, P304+P340+P312, P332+P313, P337+P313, P362+P364, P403+P233, P501
Safety data sheet (SDS) Oxford MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Salcomine is a coordination complex derived from the salen ligand and cobalt. The complex, which is planar, and a variety of its derivatives are carriers for O2 as well as oxidation catalysts.

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