Disulfuric acid

Disulfuric acid
Names
IUPAC name
Disulfuric acid
Other names
Pyrosulfuric acid, Oleum
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.069
EC Number
  • 231-976-8
MeSH Pyrosulfuric+acid
UNII
  • InChI=1S/H2O7S2/c1-8(2,3)7-9(4,5)6/h(H,1,2,3)(H,4,5,6) Y
    Key: VFNGKCDDZUSWLR-UHFFFAOYSA-N Y
  • InChI=1/H2O7S2/c1-8(2,3)7-9(4,5)6/h(H,1,2,3)(H,4,5,6)
    Key: VFNGKCDDZUSWLR-UHFFFAOYAZ
  • OS(=O)(=O)OS(O)(=O)=O
  • OS(=O)(=O)OS(=O)(=O)O
  • O=S(=O)(O)OS(=O)(=O)O
Properties
H2O7S2
Molar mass 178.13 g·mol−1
Appearance colorless
Melting point 36 °C (97 °F; 309 K)
Acidity (pKa) 2.5 (20 °C; in conc. H2SO4)
Conjugate base Disulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Disulfuric acid (alternative spelling disulphuric acid) or pyrosulfuric acid (alternative spelling pyrosulphuric acid), also named oleum, is a sulfur oxoacid. It is a major constituent of fuming sulfuric acid, oleum, and this is how most chemists encounter it. As confirmed by X-ray crystallography, the molecule consists of a pair of SO2(OH) groups joined by an oxide.