Pyrosilicate
| Names | |
|---|---|
| IUPAC name
Pyrosilicate | |
| Other names
disilicate, diorthosilicate | |
| Identifiers | |
3D model (JSmol) |
|
| ChEBI | |
| ChemSpider | |
| 326578 | |
PubChem CID |
|
CompTox Dashboard (EPA) |
|
| |
| |
| Properties | |
| O7Si2−6 | |
| Molar mass | 168.166 g·mol−1 |
| Conjugate acid | Pyrosilicic acid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
(what is ?)
Infobox references | |
A pyrosilicate is a type of chemical compound; either an ionic compound that contains the pyrosilicate anion Si
2O6−
7, or an organic compound with the hexavalent ≡O
3Si-O-SiO
3≡ group. The anion is also called disilicate or diorthosilicate.
Ionic pyrosilicates can be considered salts of the unstable pyrosilicic acid, H
6Si
2O
7. Unlike the acid, the salts can be stable. Indeed, pyrosilicates occur widely in nature as a class of silicate minerals, specifically the sorosilicates - though some sorosilicate minerals, such as gehlenite, replace one of the silicon atoms with tetracoordinated aluminium or boron, giving the isostructural anions AlSiO7−7 and BSiO7−7.
Some notable synthetic pyrosilicates include
- sodium pyrosilicate Na
6Si
2O
7, a possible component of water glass. - sodium iron(II) pyrosilicate Na
2Fe
2Si
2O
7, a potential cathode material for batteries. - sodium manganese(II) pyrosilicate Na
2Mn
2Si
2O
7, another potential cathode material.