Potassium bis(trimethylsilyl)amide

Potassium bis(trimethylsilyl)amide
Names
Preferred IUPAC name
Potassium 1,1,1-trimethyl-N-(trimethylsilyl)silanaminide
Other names
Potassium hexamethyldisilazide Potassium hexamethylsilazane
Identifiers
3D model (JSmol)
Abbreviations KHMDS
ChemSpider
ECHA InfoCard 100.102.263
UN number 3263
  • InChI=1S/C6H18NSi2.K/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1 N
    Key: IUBQJLUDMLPAGT-UHFFFAOYSA-N N
  • C[Si](C)(C)N([K])[Si](C)(C)C
Properties
KSi
2
C
6
NH
18
Molar mass 199.4831 g mol−1
Appearance White, opaque crystals
Reacts
Hazards
GHS labelling:
Danger
H314
P280, P305+P351+P338, P310
Related compounds
Other cations
Lithium bis(trimethylsilyl)amide

Sodium bis(trimethylsilyl)amide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Potassium bis(trimethylsilyl)amide (commonly abbreviated as KHMDS, Potassium(K) HexaMethylDiSilazide) or potassium hexamethyldisilazane is the chemical compound with the formula ((CH3)3Si)2NK. It is a strong, non-nucleophilic base with an approximate pKa of 26 (compare to lithium diisopropylamide, at 36).