Nitrosylsulfuric acid

Nitrosylsulfuric acid
Names
IUPAC name
Nitrosylsulfuric acid
Other names
nitrosonium bisulfate, chamber crystals
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.058
UNII
  • InChI=1S/HNO5S/c2-1-6-7(3,4)5/h(H,3,4,5) Y
    Key: VQTGUFBGYOIUFS-UHFFFAOYSA-N Y
  • InChI=1/HNO5S/c2-1-6-7(3,4)5/h(H,3,4,5)
    Key: VQTGUFBGYOIUFS-UHFFFAOYAM
  • O=NOS(=O)(=O)O
Properties
HSO4NO
Molar mass 127.08 g/mol
Appearance Pale yellow crystals
Density 1.865 g/mL in
40% sulfuric acid soln
Melting point 70 °C (158 °F; 343 K)
Boiling point Decomposes
Decomposes
Solubility Soluble in H2SO4
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidizer
Related compounds
Other anions
NOCl
Other cations
NaHSO4
Related compounds
NOBF4
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Nitrosylsulfuric acid is the chemical compound with the formula HSO4NO. It is a colourless solid that is used industrially in the production of caprolactam, and was formerly part of the lead chamber process for producing sulfuric acid. The compound is the mixed anhydride of sulfuric acid and nitrous acid.

In organic chemistry, it is used as a reagent for nitrosating, as a diazotizing agent, and as an oxidizing agent.