Methanesulfonyl chloride

Methanesulfonyl chloride
Names
Preferred IUPAC name
Methanesulfonyl chloride
Other names
Mesyl chloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.004.279
UNII
  • CS(Cl)(=O)=O
Properties
CH3SO2Cl
Molar mass 114.54 g·mol−1
Appearance colorless liquid
Odor Pungent, unpleasant
Density 1.480 g/cm3
Melting point −32 °C (−26 °F; 241 K)
Boiling point 161 °C (322 °F; 434 K) (at 730 mmHg)
Reacts
Solubility Soluble in alcohol, ether and most organic solvents
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Lachrymator, highly toxic, corrosive
Flash point >110 °C (230 °F; 383 K)
Related compounds
Other anions
Methanesulfonyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Methanesulfonyl chloride (mesyl chloride) is an organosulfur compound with the formula CH3SO2Cl. Using the organic pseudoelement symbol Ms for the methanesulfonyl (or mesyl) group CH3SO2–, it is frequently abbreviated MsCl in reaction schemes or equations. It is a colourless liquid that dissolves in polar organic solvents but is reactive toward water, alcohols, and many amines. The simplest organic sulfonyl chloride, it is used to make methanesulfonates and to generate the elusive molecule sulfene (methylenedioxosulfur(VI)).