Lead(II) sulfate

Lead(II) sulfate
Names
IUPAC name
lead(II) sulfate
Other names
Anglesite, fast white, milk white, plumbous sulfate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.028.362
EC Number
  • 231-198-9
UNII
UN number 1759 1794
  • InChI=1S/H2O4S.Pb.4H/c1-5(2,3)4;;;;;/h(H2,1,2,3,4);;;;;/q;+2;;;;/p-2 Y
    Key: PIJPYDMVFNTHIP-UHFFFAOYSA-L Y
  • InChI=1S/H2O4S.Pb.4H/c1-5(2,3)4;;;;;/h(H2,1,2,3,4);;;;;/q;+2;;;;/p-2
    Key: PIJPYDMVFNTHIP-QKXYEYSFAV
  • Key: PIJPYDMVFNTHIP-UHFFFAOYSA-L
  • [O-]S(=O)(=O)[O-].[PbH4+2]
Properties
PbSO4
Molar mass 303.26 g/mol
Appearance white solid
Density 6.29 g/cm3
Melting point 1,087 °C (1,989 °F; 1,360 K) decomposes
0.0032 g/100 mL (15 °C)
0.00425 g/100 mL (25 °C)
2.13 x 10−8 (20 °C)
Solubility insoluble in alcohol

soluble in ammonium acetate (≥ 6 mol/L)

soluble in ammonium tartrate in presence of ammonium chloride and ammonia

69.7·10−6 cm3/mol
1.877
Structure
orthorhombic, barite
Thermochemistry
103 J/degree mol
149 J·mol−1·K−1
−920 kJ·mol−1
Hazards
GHS labelling:
Danger
H302, H332, H360Df, H410
P201, P202, P260, P261, P264, P270, P271, P273, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P391, P405, P501
NFPA 704 (fire diamond)
3
0
0
Flash point Non-flammable
0.15 mg/m3
Related compounds
Other anions
Lead(II) chloride, Lead(II) bromide, Lead(II) iodide, Lead(II) fluoride
Other cations
Tin(II) sulfate, Sodium sulfate, Copper(II) sulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as fast white, milk white, sulfuric acid lead salt or anglesite.

It is often seen in the plates/electrodes of car batteries, as it is formed when the battery is discharged (when the battery is recharged, then the lead sulfate is transformed back to metallic lead and sulfuric acid on the negative terminal or lead dioxide and sulfuric acid on the positive terminal). Lead sulfate is poorly soluble in water.