Field effect (chemistry)

A field effect is the polarization of a molecule through space. The effect is a result of an electric field produced by charge localization in a molecule. This field, which is substituent and conformation dependent, can influence structure and reactivity by manipulating the location of electron density in bonds and/or the overall molecule. The polarization of a molecule through its bonds is a separate phenomenon known as induction. Field effects are relatively weak, and diminish rapidly with distance, but have still been found to alter molecular properties such as acidity.

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