Ethyl bromoacetate

Ethyl bromoacetate
Names
	Preferred IUPAC name Ethyl bromoacetate
	Other names Antol; Bromoacetic acid, ethyl ester; Ethoxycarbonylmethyl bromide; Ethyl 2-bromoacetate;
Identifiers
CAS Number	105-36-2 ;
3D model (JSmol)	Interactive image;
ChEMBL	ChEMBL1085948 ;
ChemSpider	7462 ;
ECHA InfoCard	100.002.992
EC Number	203-290-9;
PubChem CID	7748;
RTECS number	AF6000000;
UNII	D20KFB313W ;
UN number	1603
CompTox Dashboard (EPA)	DTXSID4020587 ;
	InChI InChI=1S/C4H7BrO2/c1-2-7-4(6)3-5/h2-3H2,1H3 Key: PQJJJMRNHATNKG-UHFFFAOYSA-N ; InChI=1/C4H7BrO2/c1-2-7-4(6)3-5/h2-3H2,1H3 Key: PQJJJMRNHATNKG-UHFFFAOYAE;
	SMILES BrCC(=O)OCC;
Properties
Chemical formula	BrCH2CO2CH2CH3
Molar mass	167.002 g·mol−1
Appearance	Colorless to yellow liquid
Odor	Fruity, pungent
Density	1.51 g/cm3
Melting point	−38 °C (−36 °F; 235 K)
Boiling point	158 °C (316 °F; 431 K)
Solubility in water	Insoluble
Magnetic susceptibility (χ)	−82.8·10−6 cm3/mol
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H300, H310, H330
Precautionary statements	P260, P262, P264, P270, P271, P280, P284, P301+P310, P302+P350, P304+P340, P310, P320, P321, P322, P330, P361, P363, P403+P233, P405, P501
NFPA 704 (fire diamond)	4 0 3
Flash point	47 °C (117 °F; 320 K)
Related compounds
Related esters	Methyl bromoacetate; Ethyl 3-bromopropionate; Ethyl chloroacetate; Ethyl iodoacetate; Ethyl bromodifluoroacetate; Ethyl acetoacetate;
Related compounds	Bromoacetic acid; Pepper spray; Chloropicrin;
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Ethyl bromoacetate is the chemical compound with the formula Br C H₂CO₂CH₂CH₃. It is the ethyl ester of bromoacetic acid and is prepared in two steps from acetic acid. It is a lachrymator and has a fruity, pungent odor. It is also a highly toxic alkylating agent and may be fatal if inhaled.

Names


Preferred IUPAC name Ethyl bromoacetate
Other names Antol Bromoacetic acid, ethyl ester Ethoxycarbonylmethyl bromide Ethyl 2-bromoacetate
Identifiers
CAS Number	105-36-2^Y
3D model (JSmol)	Interactive image
ChEMBL	ChEMBL1085948^Y
ChemSpider	7462^Y
ECHA InfoCard	100.002.992
EC Number	203-290-9
PubChem CID	7748
RTECS number	AF6000000
UNII	D20KFB313W^Y
UN number	1603
CompTox Dashboard (EPA)	DTXSID4020587
InChI InChI=1S/C4H7BrO2/c1-2-7-4(6)3-5/h2-3H2,1H3^Y Key: PQJJJMRNHATNKG-UHFFFAOYSA-N^Y InChI=1/C4H7BrO2/c1-2-7-4(6)3-5/h2-3H2,1H3 Key: PQJJJMRNHATNKG-UHFFFAOYAE
SMILES BrCC(=O)OCC
Properties
Chemical formula	BrCH₂CO₂CH₂CH₃
Molar mass	167.002 g·mol⁻¹
Appearance	Colorless to yellow liquid
Odor	Fruity, pungent
Density	1.51 g/cm³
Melting point	−38 °C (−36 °F; 235 K)
Boiling point	158 °C (316 °F; 431 K)
Solubility in water	Insoluble
Magnetic susceptibility (χ)	−82.8·10⁻⁶ cm³/mol
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H300, H310, H330
Precautionary statements	P260, P262, P264, P270, P271, P280, P284, P301+P310, P302+P350, P304+P340, P310, P320, P321, P322, P330, P361, P363, P403+P233, P405, P501
NFPA 704 (fire diamond)	4 0 3
Flash point	47 °C (117 °F; 320 K)
Related compounds
Related esters	Methyl bromoacetate Ethyl 3-bromopropionate Ethyl chloroacetate Ethyl iodoacetate Ethyl bromodifluoroacetate Ethyl acetoacetate
Related compounds	Bromoacetic acid Pepper spray Chloropicrin
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references