Disulfurous acid
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| Names | |||
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| IUPAC name
disulfurous acid | |||
| Other names
pyrosulfurous acid | |||
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| Properties | |||
| H2S2O5 | |||
| Molar mass | 146.13 g·mol−1 | ||
| Conjugate base | Disulfite | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Disulfurous acid, metabisulfurous acid or pyrosulfurous acid is an oxoacid of sulfur with the formula H2S2O5. Its structure is HO−S(=O)2−S(=O)−OH. The salts of disulfurous acid are called disulfites or metabisulfites. Disulfurous acid is, like sulfurous acid (H2SO3), a phantom acid, which does not exist in the free state. In contrast to disulfate (S2O2−7), disulfite has two directly connected sulfur atoms. The oxidation state of the sulfur atom bonded to three oxygen atoms is +5 and its valence is 6, while that of the other sulfur is +3 and 4 respectively.