Chromium(III) sulfate

Chromium(III) sulfate
Names
IUPAC name
Chromium(III) sulfate
Other names
Basic chromium sulfate, chromic sulfate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.030.217
EC Number
  • 233-253-2
UNII
UN number 2240 3077
  • InChI=1S/2Cr.3H2O4S.12H2O/c;;3*1-5(2,3)4;;;;;;;;;;;;/h;;3*(H2,1,2,3,4);12*1H2/q2*+3;;;;;;;;;;;;;;;/p-6 N
    Key: ANNXSSGQVXBUEI-UHFFFAOYSA-H N
  • InChI=1/2Cr.3H2O4S.12H2O/c;;3*1-5(2,3)4;;;;;;;;;;;;/h;;3*(H2,1,2,3,4);12*1H2/q2*+3;;;;;;;;;;;;;;;/p-6
    Key: ANNXSSGQVXBUEI-CYFPFDDLAL
  • anhydrous: [Cr+3].[Cr+3].[O-]S(=O)(=O)[O-].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
  • dodecahydrate: [OH2+][Cr-3]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[OH2+][Cr-3]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[O-]S(=O)(=O)[O-].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
Properties
Cr2(SO4)3 • 12H2O
Molar mass 392.16 g/mol
608.363 g/mol (dodecahydrate)

716.45 g/mol (octadecahydrate)

Appearance reddish-brown crystals (anhydrous), purple crystals (hydrated)
Density 3.10 g/cm3 (anhydrous)
1.86 g/cm3 (pentadecahydrate)
1.709 g/cm3 (octadecahydrate)
Melting point 90 °C
Boiling point >700 °C (decomposes to chromic acid)
insoluble (anhydrous)
soluble (hydrated)
Solubility soluble in alcohol
practically insoluble in acid
+11,800·10−6 cm3/mol
Hazards
GHS labelling:
Warning
H314, H317, H332, H334, H335, H340, H350, H373, H412
P201, P202, P260, P261, P264, P271, P272, P273, P280, P281, P285, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P304+P341, P305+P351+P338, P308+P313, P310, P312, P314, P321, P333+P313, P342+P311, P363, P403+P233, P405, P501
NFPA 704 (fire diamond)
1
0
0
Flash point Non-flammable
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3
REL (Recommended)
TWA 0.5 mg/m3
IDLH (Immediate danger)
250 mg/m3
Safety data sheet (SDS) MSDS
Related compounds
Other cations
Aluminium sulfate
Related double salts
Chrome alum
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Chromium(III) sulfate usually refers to the inorganic compounds with the formula Cr2(SO4)3.x(H2O), where x can range from 0 to 18. Additionally, ill-defined but commercially important "basic chromium sulfates" are known. These salts are usually either violet or green solids that are soluble in water. It is commonly used in tanning leather.