Chromium(II) selenide

Chromium(II) selenide
Names
IUPAC name
Chromium(2+) selenide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.805
EC Number
  • 234-999-1
  • InChI=1S/Cr.Se
    Key: UVZCKRKEVWSRGT-UHFFFAOYSA-N
  • [Cr]=[Se]
Properties
CrSe
Molar mass 130.96 g/mol
Appearance white to pale yellow crystalline powder
Density 6.74 g/cm3
Melting point ~1500 °C
insoluble
Structure
NiAs type (hexagonal)
P63/mmc, No. 194
a = 371 pm, c = 603 pm
Hazards
NFPA 704 (fire diamond)
1
1
1
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3
REL (Recommended)
TWA 0.5 mg/m3
IDLH (Immediate danger)
250 mg/m3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Chromium(II) selenide is an inorganic compound with the chemical formula CrSe. It crystalizes in a hexagonal structure with space group P63/mmc. It is one of many related chromium-selenium phases, including Cr2Se3, as well as Cr7Se8, Cr3Se4, Cr0.68Se, and Cr5Se8. The compound has been described as an antiferromagnet, but its inverse magnetic susceptibility does not match the behavior expected for an antiferromagnet according to the Curie–Weiss law. One suggestion was that the Néel temperature is at 320 K, as the temperature where the compound has maximum specific heat. When synthesized as single atomic layer, CrSe is ferromagnetic, with a Curie Temperature of around 280 K.