Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium

CpRuCl(PPh₃)₂
Identifiers
CAS Number	32993-05-8 ;
3D model (JSmol)	Interactive image;
ChemSpider	34560989 ;
ECHA InfoCard	100.154.457
PubChem CID	78076231;
	InChI InChI=1S/2C18H15P.C5H5.ClH.Ru/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h21-15H;1-3H,4H2;1H;/q;;-1;;+2/p-1 Key: WGQMSPWAXIDKEY-UHFFFAOYSA-M ; InChI=1/2C18H15P.C5H5.ClH.Ru/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h21-15H;1-3H,4H2;1H;/q;;-1;;+2/p-1 Key: WGQMSPWAXIDKEY-REWHXWOFAY;
	SMILES c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc[cH-1]1.[Cl-].[Ru+2];
Properties
Chemical formula	C41H35ClP2Ru
Molar mass	726.19 g/mol
Appearance	Orange solid
Melting point	135 °C (275 °F; 408 K)
Solubility in water	Insoluble
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302, H312, H315, H319, H332, H335
Precautionary statements	P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium is the organoruthenium half-sandwich compound with formula RuCl(PPh₃)₂(C₅H₅). It as an air-stable orange crystalline solid that is used in a variety of organometallic synthetic and catalytic transformations. The compound has idealized C_s symmetry. It is soluble in chloroform, dichloromethane, and acetone.

Identifiers


CAS Number	32993-05-8^Y
3D model (JSmol)	Interactive image
ChemSpider	34560989^N
ECHA InfoCard	100.154.457
PubChem CID	78076231
InChI InChI=1S/2C18H15P.C5H5.ClH.Ru/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h21-15H;1-3H,4H2;1H;/q;;-1;;+2/p-1^N Key: WGQMSPWAXIDKEY-UHFFFAOYSA-M^N InChI=1/2C18H15P.C5H5.ClH.Ru/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h21-15H;1-3H,4H2;1H;/q;;-1;;+2/p-1 Key: WGQMSPWAXIDKEY-REWHXWOFAY
SMILES c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc[cH-1]1.[Cl-].[Ru+2]
Properties
Chemical formula	C₄₁H₃₅ClP₂Ru
Molar mass	726.19 g/mol
Appearance	Orange solid
Melting point	135 °C (275 °F; 408 K)
Solubility in water	Insoluble
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302, H312, H315, H319, H332, H335
Precautionary statements	P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references